The unseeded 24-year-old achieved the feat - known as a golden set - at the start of her third-round victory over French Open runner-up Sara Errani on Court Three.
She held serve three times and broke 10th seed Errani each time to take 24 consecutive points in 15 minutes.
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Errani staged a fightback at the start of the second set and in an unforeseen twist she broke Shvedova's serve.
But Shvedova stepped up her game to tie up a 6-0, 6-4 victory.
'Today I laid a golden egg!' she wrote on Twitter.
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